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Conversion of Oil Field Produced Brine
to Fresh Water


OVERVIEW

This report discusses the feasibility of treating brine from oil and gas operations to make it usable for beneficial purposes. A separate section on unconventional oil and gas operations discusses the increased demand for water resources and the need for recovery of fresh water and re-use of brine byproducts from this activity.  The study was conducted by the Department of Petroleum Engineering and the Texas Water Resources Institute at Texas A&M University, College Station Texas and CH2M Hill Company.

Motivation for the Research

Texas has long been one of the top petroleum producing states in the nation. As fields have matured, more brine water is produced along with the petroleum resource. More brine water is being re-injected as well, to sustain production, prevent subsidence, and to dispose of excess produced brine. Texas has long been struggling with a lack of water resources and as the population of the state grows, more demand is being placed upon surface and ground water sources of fresh water. As these issues become more important, more attention is turning to recovery of fresh water from these brine byproducts of O&G activity.

Unfortunately produced brine can not be used without treatment to remove harmful substances. Untreated produced brine has contaminants that make it unpalatable for humans or livestock. Re-injection of the brine back into the formation from where it was produced has been the least expensive; hence preferred disposal method for brines. Other issues include:

(1)   Desalination of wastewater such as oil field brine can be expensive.

(2)   Oil and gas companies are not water providers.

(3)   Less expensive surface and ground water has provided adequate supplies of fresh water for communities, livestock and agriculture interests.

Most of these issues are the result of the characteristics of oil field brine. Large quantities of produced water are brought to the surface in Texas as a result of various natural resource extraction activities. The composition of this produced fluid is dependent on whether crude oil or natural gas is being produced and generally includes a mixture of either liquid or gaseous hydrocarbons, produced water, dissolved or suspended solids, produced solids such as sand or silt, and injected fluids and additives that may have been placed in the formation as a result of exploration and production activities.

The Texas Water Development Board is seeking to determine whether desalination of produced brine offers promise as a source of fresh water resources. Research is currently underway at a number of companies to assess the economic and technological feasibility of desalting this product water to develop water of sufficient quality to meet certain local water supply needs and to allow consideration of disposal options other than well injection. At Texas A&M University, a team of scientists and engineers is working on this concept and is working to further the technology and put it into commercial practice.

Specific research needs are harder to prioritize. For the past three years A&M has worked to find technologies to employ in desalination and to outline ways to establish a value for the resource that is recovered by this treatment. The research has found that the technology is available to desalinate certain brines produced in petroleum operations [1]. However that technology needs to be improved, the value of fresh water and local water supply needs must be established, and the environmental and regulatory issues associated with beneficial use must be addressed.

Recommendations for the Advancement of Desalination Technology

Our feasibility study recommends a number of steps to help advance desalination technology. Technology demonstrations or “road shows” could bring new concepts of pure water to communities in need. The TWDB should continue to lead by example and should encourage other State Agencies to address water needs in a comprehensive fashion and to communicate, remove paperwork barriers, and advance worthy projects.

Collaboration should not be limited to just Texas organizations. The Rio Grande Basin Initiative is one example of economic development programs that seeks new approaches to solving problems [44] common to the states of New Mexico and to Texas. A research alliance has been established that includes these two states plus Arizona named CHIWAWA (Consortium for Hi-Technology Investigations in Water and Wastewater) [45]. The purpose of this initiative is to create sustainable urban and rural water supplies and protect environmental quality by conducting innovative, collaborative research, education and training programs in inland desalination technology, concentrate disposal and water resources management. A consortium including New Mexico State University, The Texas A&M University System, and the University of Texas at El Paso and two water utilities, the Cities of El Paso and Alamogordo are pooling advanced expertise and experience in arid environment water resource management to address pressing technological, management and training issues related to inland desalination, source water characterization and concentrate and water resources management.

Finally the efforts to address the needs of local communities at the local level is paramount especially in the regions of the State where fresh water resources are insufficient for current or future needs. This report on the new technology of desalination and re-use of oil field brine is only a part of the effort necessary to develop commercial programs. There must be efforts by all to communicate to the users. This involvement with the community is expected to make any proposed projects more likely to be accepted and thus support our efforts to create these new water resources more effectively.

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