Department of Petroleum Engineering Dwight Look College of Engineering Texas A & M University Texas Engineering Experiment Station Global Petroleum Research Institute Petroleum Engineering

 

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Conversion of Oil Field Produced Brine
to Fresh Water


WATER RESOURCES ASSOCIATED WITH
UNCONVENTIONAL O&G DEVELOPMENT
 

Energy production represented by oil and gas extraction has been one of the major industries in Texas for more than 100 years. The fields that were discovered during this time are nearing their economic limit. One reason that O&G operators are interested in desalination of produced water is that it has the chance of reducing operating costs of their wells, and extending their lifetimes. Within the last 10 years however, unconventional reservoirs are being brought on production as new technology makes their development economical. Most of the attention to unconventional resources has been focused on coal bed natural Gas (CBNG). Figure 12 shows CBNG resources in Texas and nationwide. These resources have an estimated 750 trillion cubic ft of natural gas.

The increase in importance of CBNG and other unconventional resources is the result of a combination of factors, tax breaks for exploration, research funding that triggered new technology in imaging, horizontal wells, and hydraulic fracturing and high gas prices. As the figure shows, much of the energy play is in environmentally sensitive areas, in the West public lands, and in the East, populated areas that have not experienced oil and gas“booms”.


 

 Figure 12. Unconventional Shale Gas Resources in the U.S.

Despite the issues related to the impact of drilling in environmentally sensitive areas, and despite the needs for technology advances, most industry specialists believe that this source of energy for the U.S. is destined to become more and more important.  Figure 13 shows a chart resulting from a study by the Petroleum Technology Council )PTTC) [46]. The contribution of unconventional resources increases steadily over the next 50 years until it represents more than 50% of the U.S, natural gas needs.

Figure 13 shows gas production forecasts for the lower 48 states and Canadian Fields for the next 20 years. Source PTTC [49] 

In Texas, the most activity is in the Barnett Shale play in North Central part of the state. In the past three years, the drilling boom in the Barnett Shale has become the most active area in the U.S. The field, the largest active gas field in Texas, now produces more than 220 Bcf of natural gas per year.

Drilling activity isn’t limited to Texas however. Unconventional energy resources in Oklahoma include Hunton de-watering and coal bed methane (CBNG activity in the Arkoma and Cherokee basins [7,8] CBNG active in Oklahoma's Arkoma Basin produced about 70 Bcf of gas cumulatively through mid-2003. About two-thirds of this production is from vertical wells, but horizontal production is rapidly overtaking that from vertical. Cherokee Basin CBNG cumulative production is about 45 Bcf, all from vertical wells. CBNG well in southeast Kansas are now producing about 10 Bcf per year, and activity is strong. Arkansas CBNG production is just now begun to increase.

Water Resources Used in Energy Production

 The connection between unconventional energy resources and water resources is typified by the photograph in Figure 14. It shows a well fracturing operation in the Barnett Shale using fresh water from the municipality of Cleburne, Johnson County Texas. Cleburne sells water to operators at retail rates to stimulate Barnett Shale wells. A horizontal well fracturing operation uses on average 5 million gallons of water to create vertical fractures that intersect natural fissures in the shale. Flow back of the water, now containing mineral salts from the underground formation, occurs over a period of several days to months.  

Figure 14 is a photograph of a fracturing operation in the Barnett Shale.

Flow back water must be captured in lined pits and transported to off site disposal. Salinity characteristics of this brine vary greatly, depending on the amount of flow back water, the zone that has been discharging the water, and the formation water content as a component of the fracturing water. Table 10 shows typical analytical data from water transport trucks carrying brine to off-site disposal. Total dissolved salts are in excess of 100,000 ppm. Total suspended solids (TSS) are likewise quite high averaging almost 200 ppm for transport samples and more than 15,000 for the pit sample.

The issue is that all of the fresh water must be transported in to the site, then all of the flow back brine stored, re-loaded in transports and trucked to disposal wells that be dozens of miles away. The brine water is then injected and lost permanently from the environmental natural water.

Table 10. Composition of Typical Flow Back Water from Barnett Shale [47]

The Social Cost of Energy Production

The issue of supplying adequate water resources for communities intersects with the need for water resources for energy production for those communities. Efforts by Texas A&M and others to reduce the use of water in energy production and to make fresh water available for those communities is part of the process of sustainable natural resource development.

Texas, in the 21st century is becoming a different society than most adults recall growing up. In almost every county in Texas, the population is shrinking. The urban centers and the counties near the urban areas are absorbing practically 100% of the state’s population growth. On the other hand, almost 100% of the population would rather live in a small community. It is only because there are few jobs and inadequate social infrastructure; most end up in the cities.

When economic booms come to local communities, many times its leaders are unable to cope with the change. The role of state and federal government in local communities is diminishing as funds for economic development are stretched. It is becoming the responsibility of the communities themselves to take lead in their own survival and development. Unconventional energy development brings both good and bad changes to these cities. The ability to recover water resources from energy development helps to accommodate the changes it brings.

There is new technology for developing new sources of fresh water for the community.  Two examples are the desalination of brackish water from underground aquifers to make it potable and the treatment and desalination of oil field produced water to make it usable for livestock, agriculture and industrial uses.

Studies have shown that it is extremely important that the user (defined as local community who might have a use for the water) be included in the change process that comes from adoption of this new technology. The user’s interest in anyone’s recommended systems is very important because these interests are the basis for the system’s acceptance and adoption.

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